Publications

A pilot-plant for the selective recovery of magnesium and calcium from industrial waste brines

Desalination (Volume 517)
December 2021
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The problem of brines disposal has raised great interest towards new strategies for their valorisation through the recovery of minerals or energy. As an example, the spent brine from ion exchange resins regeneration is often discharged into rivers or lakes, thus impacting on the process sustainability. However, such brines can be effectively reconcentrated, after removal of bivalent cations, and reused for the resins regeneration. This work focuses on developing and testing a pilot plant for selective recovery of magnesium and calcium from spent brines exploiting a novel proprietary crystallization unit. This is part of a larger treatment chain for the complete regeneration of the brine, developed within the EU-funded ZERO BRINE project. The pilot crystallizer was tested with the retentate of the nanofiltration unit processing the spent brine from the industrial water production plant of Evides Industriewater B.V. (Rotterdam, The Netherlands). Magnesium and calcium hydroxide were selectively precipitated by adding alkaline solution in two consecutive steps and controlling reaction pH. Performance was assessed in terms of recovery efficiency and purity of produced crystals, observing in most investigated cases a recovery of about 100% and 97% and a purity above 90% and 96%, for magnesium and calcium hydroxide, respectively.

A simulation tool for ion exchange membrane crystallization of magnesium hydroxide from waste brine

Chemical Engineering Research and Design (Volume 173)
September 2021
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Increasing attention is nowadays paid to the management and valorisation of industrial waste brines aiming also at the recovery of raw materials. Magnesium has been listed as a Critical Raw Material by EU, prompting researchers to investigate novel routes for its recovery. Within this framework, a novel Crystallizer with Ion Exchange Membrane (CrIEM), is proposed as an innovative way to recover magnesium from industrial waste brines exploiting low-cost alkaline reactants. In the present work, a novel mathematical model of the CrIEM process is proposed to provide a useful tool for its design in different working conditions. Batch and feed & bleed continuous configurations have been investigated taking into account: (i) the variation of the alkaline and brine concentration in their own collection tanks over time and (ii) the spatial mono-dimensional (1D) steady-state description of the main phenomena that occur inside the CrIEM. Original experimental data, from ad-hoc laboratory tests, and literature information were used to validate the proposed model both in the batch and continuous feed & bleed configuration. A good agreement between model predictions and experimental/literature data was found for both cases, thus proving the reliability of the proposed model for the design of the CrIEM reactor.

Application of LCA and LCC in the early stages of wastewater treatment design: A multiple case study of brine effluents

Journal of Cleaner Production (Volume 307)
July 2021
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Technological developments are opening new avenues to facilitate the circular economy through resource recovery from industrial wastewater. This paper presents the use of Life Cycle Assessment (LCA) and Life Cycle Costing (LCC) in the development of technology solutions for the treatment of brine wastewater and recovery of by-products. Four industrial case studies are assessed that apply different innovative technology configurations, to treat the brines and recover the water, salts and mineral compounds. The assessment focusses on identifying hotspots and potential design improvements for the four case studies. In addition, the development of a unified approach for prospective LCA and LCC is illustrated to promote robustness and consistency in the analysis of the four systems. The analysis reveals that the impact and cost of treatment is highly dependent on the wastewater composition. Critically, whether the recovery of compounds and deionised water can counteract the impact and cost of the treatment systems. The early analysis suggests that this is possible for two of the cases studies. Estimates of the GHG emissions for the initial system analysis, range from 10 to 17 kg CO2e/m3, whilst costs range from €10/m3 to €25/m3. However, both are expected to decrease at full scale and are sensitive to costs of energy, chemicals and revenue from recovered by-products. The LCA’s highlight chemical and energy consumption as critical hotspots. Design considerations therefore focus on the reduction of chemicals, reuse or switching to lower impact chemicals, and maximising by-product recovery, and using renewable energy.

High Purity Recovery of Magnesium and Calcium Hydroxides from Waste Brines

Chemical Engineering Transactions (Volume 86)
June 2021
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Direct disposal of concentrate brines, generated by many industrial sectors, causes serious environmental concerns. An industrial sector that produces high concentrate brines is softening water industry, in particular during the regeneration of ion exchange resins. These brines are mainly rich in sodium, magnesium and calcium chlorides, thus, their regeneration, by removal/recovery of magnesium and calcium, can be a valuable option to turn the brine into a source of minerals and reduce disposal costs and environmental concerns. In this regards, one of the goals of EU-funded ZERO BRINE project is to develop a treatment chain for the valorization and regeneration of spent brines from water softening plants. The treatment chain consists of Nanofiltration, crystalization and evaporation to regenerate spent brines and recover high purity magnesium and calcium hydroxides. In this work, a wide experimental campaign was carried out to recover high purity magnesium and calcium via selective chemical precipitation of relevant hydroxides adding by injection of an alkaline solution in two consecutive steps at controlled pH. Precipitations were performed using synthetic brine solution, mimicking the retentate produced by nanofiltration, some of them were carried out considering a pre-treatment step to remove bicarbonate ions.

Developing social life cycle assessment based on corporate social responsibility: A chemical process industry case regarding human rights

Technological Forecasting and Social Change (Volume 165)
April 2021
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Social Life Cycle Assessment (S-LCA) uses a life cycle perspective to assess social impacts of products, and the S-LCA guidelines describe developing the system boundaries based on a factory-level perspective. However, such a perspective may exclude stakeholders with a negative social performance which are cooperating with a factory but are not directly involved with the product under study, and it can result in a step back on corporate social responsibility (CSR). Our study aimed to align S-LCA with the CSR concept. Therefore, we designed a case study for the manufacturing sector in which we practiced expanding the system boundaries of S-LCA. Our results showed larger social risks after expanding the system boundaries due to subsidiary and supplier companies located in countries with less strict regulations than the Netherlands, which is where the main organizations and parent company existed. We conclude that system boundaries expansion can result in more complete picture of the involved organizations, and lead practitioners to approach S-LCA with the goal of improving social conditions and identify companies which deserve excellent or poor social scores. Its usefulness is mostly expected when S-LCA practitioners aim to identify social hotspots in supply chains in socially sensitive markets.

Aspects of environmental impacts of seawater desalination: Cyprus as a case study

Desalination and Water Treatment (Volume 211)
January 2021
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Cyprus relies on seawater desalination for a large part of its drinking water supply, with reverse osmosis providing more than 95% of the total desalination capacity in the country. Nevertheless, the environmental impacts of desalination for the Cypriot environment remain poorly understood. Using a combination of mining existing governmental and corporate survey data and reports, this study explores the scale of desalination in Cyprus, the impacts on the coastal marine environment and its overall carbon footprint. Surveys of Posidonia oceanica seagrass meadows show strongly reduced density of shoots and leaf surface area, respectively. Analysis of the available data relating to the overall production of desalinated water and energy consumption reveals that 68.7 million m3 of desalinated water were produced in Cyprus in 2017, resulting in the release of 160 ktons of CO2 equivalent, representing around 2% of the total carbon emissions in Cyprus. The results are directly applicable for understanding the impacts of brine discharge on seagrass meadows, one of the most common types of Mediterranean seabed ecosystems and useful for providing guidance to decision makers as they are striving to achieve a zero-carbon economy. strategies for achieving greater sustainability in terms of reduced CO2 emissions and less brine discharge are discussed.

Implementing sustainable design theory in business practice: A call to action

Journal of Cleaner Production (Volume 273)
November 2020
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The intensification of industrial activity within an unsustainable development paradigm caused an alarming environmental crisis intertwined with societal problems on a global scale. Sustainable design theory contains an extensive body of knowledge on how these environmental and societal issues can be addressed by rethinking industrial products, processes and, more broadly, how organizations operate in the context of a more sustainable socio-economic system. Nevertheless, evidence shows that implementing these ideas is a problematic yet under addressed aspect, resulting in a gap between abstract speculations and concrete action. In this study, we focus on this critical gap by looking at how existing theory of sustainable design is implemented in business practice. To this end, we conduct a literature review followed by interviews with twenty international experts, to uncover their knowledge related to relevant project experiences. The outcome is a framework that integrates existing sustainable design theory with important business concepts, clustering it into four literature streams:ecodesign, product service system design, sustainable business model design and collaborative ecosystem design. These streams correspond to four levels of design for sustainable innovation. The framework also encompasses a set of themes related to the implementation of sustainable design theory in business practice across the aforementioned four levels. Based on this, we outline our contributions to theory and practice, and pinpoint recommendations for academic researchers, industrial designers and business managers who want to leverage their professional position to play an active role in the transition toward sustainable development.

Techno-economic analysis of integrated processes for the treatment and valorisation of neutral coal mine effluents

Journal of Cleaner Production (Volume 270)
October 2020
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The disposal of highly-concentrated neutral coal mine effluents into the environment constitutes a severe threat to the natural ecosystem. This work proposes and compares five novel treatment chains to purify the effluent and recover raw materials. The chains present different combinations of pre-treatment and concentration technologies. In all cases, the solution sent to the concentration step is concentrated up to saturation to recover water and sodium chloride.

Concerning the technical performances, the treatment chains are compared in terms of total energy demand and salt recovery. Furthermore, the economic feasibility assessment is performed via a novel global parameter, i.e. the levelized cost of the produced NaCl crystals (Levelized Salt Cost, LSC).

The energetic and economic analysis of the chains highlighted that the thermal energy demand of the concentration technology covers the highest share of the total demand and the relevant costs are among the highest expenditures. Also, the revenues given by Mg(OH)2 production were found to play a key role in offsetting the treatment costs. Among the treatment chains analysed, the one composed by two nanofiltration units and two crystallizers in the pre-treatment step and a multi-effect distillation unit in the concentration step showed the highest recovery of NaCl and turned out to be the most economically feasible. The relevant LSC (∼100 $/tonNaCl) was the lowest and it was comparable with the lower bound of the current range of price of high-purity NaCl crystals.

In conclusion, the findings of this work contribute to improving the sustainability of the coal mine industrial sector, by proposing economically feasible solutions for the treatment and valorisation of its neutral effluent.

A Novel Ionic Exchange Membrane Crystallizer to Recover Magnesium Hydroxide from Seawater and Industrial Brines

Membranes (Volume 10)
October 2020
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A novel technology, the ion exchange membrane crystallizer (CrIEM), that combines reactive and membrane crystallization, was investigated in order to recover high purity magnesium hydroxide from multi-component artificial and natural solutions. In particular, in a CrIEM reactor, the presence of an anion exchange membrane (AEM), which separates two-compartment containing a saline solution and an alkaline solution, allows the passage of hydroxyl ions from the alkaline to the saline solution compartment, where crystallization of magnesium hydroxide occurs, yet avoiding a direct mixing between the solutions feeding the reactor. This enables the use of low-cost reactants (e.g., Ca(OH)2) without the risk of co-precipitation of by-products and contamination of the final crystals. An experimental campaign was carried out treating two types of feed solution, namely: (1) a waste industrial brine from the Bolesław Śmiały coal mine in Łaziska Górne (Poland) and (2) Mediterranean seawater, collected from the North Sicilian coast (Italy). The CrIEM was tested in a feed and bleed modality in order to operate in a continuous mode. The Mg2+ concentration in the feed solutions ranges from 0.7 to 3.2 g/L. Magnesium recovery efficiencies from 89 up to 100% were reached, while magnesium hydroxide purity between 94% and 98.8% was obtained.

Experimental and theoretical characterization of commercial nanofiltration membranes for the treatment of ion exchange spent regenerant

Journal of Membrane Science (Volume 606)
July 2020
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This work presents a joint experimental and simulation campaign aimed at characterizing two nanofiltration membranes (TS80 and NF270) in the presence of a multi-ionic water solution simulating the spent regenerant of cationic ion exchange resins employed for water softening. We identified the membrane parameters, which allowed for predicting the performances through the Donnan Steric Pore Model with Dielectric Exclusion. A good agreement between model and experimental trends of rejection as a function of the applied pressure was observed (error < 15%). The analysis of trans-membrane fluxes and exclusion coefficients showed that dielectric exclusion was the crucial mechanism for the ionic partition. In fact, the lower pore dielectric constant found for TS80 justified the higher rejections to divalent cations with respect to NF270. Moreover, negative charge densities were found for both membranes, because of the high concentration of chloride ions in the feed, which likely adsorbed onto the membrane. However, it was observed that the experimental rejections did not change significantly with the feed pH. This result, in line with the minor role of the Donnan exclusion resulting from the model, suggested that the membrane performances were not much affected by the charge density at high feed ionic strengths (~1 M).

Addressing the design-implementation gap of sustainable business models by prototyping: A tool for planning and executing small-scale pilots

Journal of Cleaner Production (Volume 255)
May 2020
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Next to the redesign of industrial products and processes, sustainable business model innovation is a strategic approach to integrate environmental and social concerns into the objectives and operations of organizations. One of the major challenges of this approach is that many promising business model ideas fail to reach the market, which is needed to achieve impact. In the literature, the issue is referred to as a “design-implementation gap.” This paper explores how that critical gap may be bridged. In doing so, we contribute to sustainable business model innovation theory and practice. We contribute to theory by connecting sustainable business model innovation with business experimentation and strategic design, two innovation approaches that leverage prototyping as a way to iteratively implement business ideas early on. Using a design science research methodology, we combine theoretical insights from these three literatures into a tool for setting up small-scale pilots of sustainable business models. We apply, evaluate, and improve our tool through a rigorous process by working with nine startups and one multinational company. As a result, we provide normative theory in terms of the sustainable business model innovation process, explaining that piloting a prototype forces organizations to simultaneously consider the desirability (i.e., what users want), feasibility (i.e., what is technically achievable), viability (i.e., what is financially possible), and sustainability (i.e., what is economically, socially and environmentally acceptable) of a new business model. Doing so early on is functional to bridge the design-implementation gap of sustainable business models. We contribute to practice with the tool itself, which organizations can use to translate sustainable business model ideas defined “on paper” into small-scale pilots as a first implementation step. We encourage future research building on the limitations of this exploratory study by working with a larger sample of companies through longitudinal case studies, to further explain how these pilots can be executed successfully.

Towards the implementation of circular economy in the water softening industry: A technical, economic and environmental analysis

Journal of Cleaner Production (Volume 255)
May 2020
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To reduce the environmental impact of the industrial sectors, circular strategies should be implemented to purify the effluents and recover raw materials. In this context, a novel integrated methodological approach is proposed to identify the most suitable strategy to improve the sustainability of the water softening industry via the treatment and recycling of the produced wastewater. Different concentration technologies and energy supply systems are compared to find economically feasible and environmentally friendly treatment systems. The investigated chains present the same pre-treatment step (nanofiltration and crystallization) and different concentration technologies: Multi-Effect Distillation (MED), Membrane Distillation (MD) and the coupling of Reverse Osmosis and Membrane Distillation (RO-MD). In the case of electricity supplied by the grid, the MED and the RO-MD chain are economically competitive with the state of the art (Levelized Brine Cost (LBC) between 4 and 6$/m3, lower than the regenerant solution cost, equal to 8$/m3). Moreover, the specific CO2 emissions due to the energy required by the treatment processes (10.8 kgCO2/m3regenerant for the MED chain and 16.7kgCO2/m3regenerant for the RO-MD chain) are lower than those produced by the current system (19.7kgCO2/m3regenerant). Varying the feed flow rate, the MED-chain is more feasible at larger plant sizes for its lower energy demand, while the chain including RO-MD shows lower costs at smaller plant sizes for its lower investment costs. When a photovoltaic-battery system is coupled, both the MED-chain and RO-MD-chain show a CO2 emission reduction of more than 75% with respect to the state of the art. Furthermore, their LBC values are very competitive, especially if the plant is located in a region with high solar potential.

Social life cycle assessment of brine treatment and recovery technology: A social hotspot and site-specific evaluation

Sustainable Production and Consumption (Volume 22)
April 2020
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Environmental pollution, resource scarcity, and freshwater shortage are critical world challenges facing humanity. Process industry produces large amounts of brine, a waste water with a high salinity level and often critical raw materials. This study applies the social life cycle assessment (S-LCA) to quantify societal benefits and risks in developing brine treatment systems. S-LCA is implemented for hotspot and site-specific levels on four case studies of the Zero Brine project. Hotspot analysis focused on the major commodities. Social Hotspot Database was used as source for data and endpoint indicators. In addition, site-specific analysis regarded the social performance of the case studies companies; interviews and questionnaires were performed with representatives of the four case studies. The collected data were converted to scores with subcategory assessment method and performance reference points. The results show that for all case studies “Labor rights and decent work” and “Health and safety” indicators result in the largest impacts due to imports of commodities from developing countries. Site-specific results show that the overall social sustainability performance of the case study companies is at a good level. The only potential areas for improvement are the “Occupational accidents” and “Contribution to the local community”. The former are minimally higher for silica plant and higher for coal mine in relation to these sectors average accidents rates. Furthermore, the coal mine company can contribute more to the local community and reduce conflicts concerning environmental impacts at the city level. Common identified hotspots among the case studies are: China, India and Congo. Reducing imports from these countries will significantly improve the societal performance of the brine systems.

Desalination brine disposal methods and treatment technologies – A review

Science of The Total Environment (Volume 693)
November 2019
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Brine, also known as concentrate, is the by-product of the desalination process that has an adverse impact on the environment due to its high salinity. Hence, viable and cost-effective brine management systems are needed to reduce environmental pollution. Currently, various disposal methods have been practiced, including surface water discharge, sewer discharge, deep-well injection, evaporation ponds and land application. However, these brine disposal methods are unsustainable and restricted by high capital costs and non-universal application. Nowadays, brine treatment is considered one of the most promising alternatives to brine disposal, since treatment results in the reduction of environmental pollution, minimization of waste volume and production of freshwater with high recovery. This review article evaluates current practices in brine management, including disposal methods and treatment technologies. Based upon the side-by-side comparison of technologies, a brine treatment technology framework is introduced to outline the Zero Liquid Discharge (ZLD) approach through high freshwater recovery and wastewater volume minimization. Furthermore, an overview of brine characteristics and its sources, as well as its negative impact on the environment is discussed. Finally, the paper highlights future research areas for brine treatment technologies aiming to enhance the effectiveness and viability of desalination.

Combined membrane and thermal desalination processes for the treatment of ion exchange resins spent brine

Applied Energy (Volume 254)
November 2019
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The disposal of industrial wastewater effluents represents a critical environmental issue. This work focuses on the treatment of the spent brine produced by the regeneration of ion exchange resins employed for water softening. For the first time, a comprehensive techno-economic assessment and an analysis of the energy requirements of the treatment chain are carried out, via the simulation of ad hoc implemented models. The chain is composed of nanofiltration, double-stage crystallization and multi-effect distillation. The valuable product is the brine produced by the multi-effect distillation, which can be re-used for the regeneration. Therefore, the treatment chain’s economic feasibility is evaluated via the Levelized Brine Cost, which includes the terms of cost and revenue of every unit in the chain. Varying the nanofiltration recovery, the treatment system always turns out to be economically competitive, since the Levelized Brine Cost is lower than the current cost of the fresh regenerant solution (8 $/m3). In particular, the lowest value of 4.9 $/m3 is found for a nanofiltration recovery of 25%. Moreover, the cost of the reactant used in the crystallization and the revenues of Mg(OH)2 and Ca(OH)2 play a prominent role in all scenarios. Regarding the energy demand, the thermal energy required by the evaporator is the main contribution and covers more than 30% of the operating costs (excluding the cost of the crystallization reactant, which is balanced by the hydroxides revenues). Therefore, the costs can be significantly reduced when waste heat is available in the industrial site. Overall, the treatment chain is economically feasible and allows reducing the industrial environmental impact by recycling waste streams and waste heat.

Desalination brine disposal methods and treatment technologies – A review

Science of The Total Environment (Volume 693)
November 2019
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Brine, also known as concentrate, is the by-product of the desalination process that has an adverse impact on the environment due to its high salinity. Hence, viable and cost-effective brine management systems are needed to reduce environmental pollution. Currently, various disposal methods have been practiced, including surface water discharge, sewer discharge, deep-well injection, evaporation ponds and land application. However, these brine disposal methods are unsustainable and restricted by high capital costs and non-universal application. Nowadays, brine treatment is considered one of the most promising alternatives to brine disposal, since treatment results in the reduction of environmental pollution, minimization of waste volume and production of freshwater with high recovery. This review article evaluates current practices in brine management, including disposal methods and treatment technologies. Based upon the side-by-side comparison of technologies, a brine treatment technology framework is introduced to outline the Zero Liquid Discharge (ZLD) approach through high freshwater recovery and wastewater volume minimization. Furthermore, an overview of brine characteristics and its sources, as well as its negative impact on the environment is discussed. Finally, the paper highlights future research areas for brine treatment technologies aiming to enhance the effectiveness and viability of desalination.

Social Life Cycle Assessment of Brine Treatment in the Process Industry: A Consequential Approach Case Study

Sustainability (Volume 11)
October 2019
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Social life cycle assessment (SLCA) was developed to complement the environmental life cycle assessment (LCA) and economic assessment. Contrary to LCA, SLCA is not yet standardized, and the consequential approach is little discussed in literature. This study aims to perform a consequential SLCA and investigate the applicability of the method in industrial decision making. The aforementioned assessment is done within the Zero Brine project, which works on zero liquid discharge technology for water, salt, and magnesium recovery from brine efluents. The developed SLCA systems are gate-to-gate, and the analysis is performed at two levels: Hotspot and site-specific. The system boundaries consist of a demineralized water (DW) production company, a chlor-alkali company, an electricity provider, a magnesium distributor in the Netherlands, and a Russian mining company. The latter exists only in the boundaries before the change due to the Zero Brine project, because recovered magnesium is expected to replace the Russian magnesium imported in the Netherlands. Within the system boundaries, the stakeholders contributing the most are the DW and the magnesium distributor companies. The former produces the brine and thus recovers the magnesium and salt. The latter is the exclusive distributor of Russian magnesium in the Netherlands. Overall, we find that the recovered magnesium results in improving social performance mainly in “Freedom of association and collective bargaining”, “Fair salary”, and “Health and Safety” due to decreasing the dependency of the Netherlands on Russia, while increasing operation in a country with much stronger environmental regulation and corporate commitment to sustainability issues. Modelling with SLCA may not result in the expected societal benefits, as the Russian community and workers may not benefit due to the large geographical boundaries of the system under study. Nevertheless, the application of the consequential approach can be considered suitable, yet complicated, for offering decision makers adequate social information. We recommend that decision makers in the DW company invest in magnesium recovery and that decision makers in the magnesium distributor company distribute the recovered magnesium.

From the allocation debate to a substitution paradox in waste bioenergy life cycle assessment studies

The International Journal of Life Cycle Assessment (Volume 25)
August 2019
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Abstract not available.

Techno-economic assessment of multi-effect distillation process for the treatment and recycling of ion exchange resin spent brines

Desalination (Volume 456)
April 2019
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A treatment chain including nanofiltration, crystallization and multi-effect distillation (MED) is for the first time proposed for the treatment of an effluent produced during the regeneration of Ion Exchange resins employed for water softening. The goal is to recover the minerals and to restore the regenerant solution to be reused in the next regeneration cycle. MED is the most crucial unit of the treatment chain from an economic point of view. A techno-economic analysis on the MED unit was performed and a novel performance indicator, named Levelized Brine Cost, was introduced as a measure of the economic feasibility of the process. Different scenarios were analysed, assuming different thermal energy sources and configurations (plane-MED or MED-TVC). It was found that the plane-MED fed by waste-heat at 1 bar is very competitive, leading to a reduction of 50% of the fresh regenerant current cost. Moreover, the thermal energy cost of 20US$/MWhth was identified as the threshold value below which producing regenerant solution in the MED is economically more advantageous than buying a fresh one. Overall, MED allows reducing the environmental impact of the industrial process and it results competitive with the state of the art for a wide range of operating conditions.

Industrial Symbiosis: towards a design process for eco-industrial clusters by integrating Circular Economy and Industrial Ecology perspectives

Journal of Cleaner Production (Volume 216)
April 2019
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Industrial Symbiosis (IS) is a collective approach to competitive advantage in which separate industries create a cooperative network to exchange materials, energy, water and/or by-products. By addressing issues related to resource depletion, waste management and pollution, IS plays an important role in the transition towards sustainable development. In the literature, two conceptual perspectives on IS can be identified: the Industrial Ecology (IE) and the Circular Economy (CE) perspective. Despite the recognition of these two perspectives, their relationship remains unclear and explicit attempts to develop an integrated perspective have not been made yet. Consequently, the goal of this research is to highlight and start addressing this critical gap of knowledge in order to support future research and practice geared towards the design of new IS clusters. We pose the following research question: How can the IE and CE perspectives on IS be combined in order to support the design of IS clusters? To this end, we first investigate the two perspectives more in depth and compare them in terms of nature, features and relevance for the study of IS. This is done by applying them as conceptual lenses for the analysis of the same case study, an existing IS cluster. The comparative analysis provides insights into how the two perspectives differ, ultimately demonstrating that they are complimentary and both necessary to fully describe an IS cluster. While the CE perspective is more suitable to explain how a cluster functions from a business standpoint in the operating phase, the IE perspective is more suitable to explain its development over time and its impacts on the environment, the economy and society. Building upon the outcomes of the comparative analysis, we leverage on the discipline of Strategic Design and integrate the two perspectives into a process for designing new IS clusters. We suggest two directions for future research. First, improving our comparative analysis of the two perspectives by looking at a wider sample of IS clusters of different sizes and in different contexts. Second, focusing with more specificity on the issue of how IS clusters can be designed, potentially by trying to apply the process we propose on a real case aimed at designing a new IS cluster.

Towards the first proof of the concept of a Reverse ElectroDialysis – Membrane Distillation Heat Engine

Desalination (Volume 453)
March 2019
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The coupling of Reverse Electrodialysis with Membrane Distillation is a promising option for the conversion of waste heat into electricity. This study evaluates the performances of the integrated system under different operating conditions, employing validated model and correlations. This work provides a detailed description of the behaviour of a real RED-MD heat engine and indicates the set of inlet concentrations, velocities and equipment size which returns the highest cycle exergy efficiency. These operating conditions were selected for the pilot plant developed within the EU-funded project RED Heat to Power. For the first time, a perspective analysis was also included, considering highly performing RED membranes and future MD module. Relevant results indicate that technological improvements may lead to interesting system performance enhancement, up to an exergy efficiency of 16.5%, which is considerably higher than the values reported in literature so far.

Social life cycle assessment of brine treatment and recovery technology: A social hotspot and site-specific evaluation
Tsalidis et al.
Sustainable Production and Consumption. 2020
Techno-economic assessment of multi-effect distillation process for the treatment and recycling of ion exchange resin spent brines
Micari et al.
Desalination. 2019
Combined membrane and thermal desalination processes for the treatment of ion exchange resins spent brine
Micari et al.
Applied Energy. 2019
Towards the first proof of the concept of a Reverse ElectroDialysis – Membrane Distillation Heat Engine
Micari et al.
Desalination. 2019
Addressing the design-implementation gap of sustainable business models by prototyping: A tool for planning and executing small-scale pilots
Baldassarre et al.
Journal of Cleaner Production. 2020
Implementing sustainable design theory in business practice: A call to action
Baldassarre et al.
Journal of Cleaner Production. 2020
A Novel Ionic Exchange Membrane Crystallizer to Recover Magnesium Hydroxide from Seawater and Industrial Brines
La Corte et al.
Membranes. 2020
Aspects of environmental impacts of seawater desalination: Cyprus as a case study
Xevgenos et al.
Desalination and Water Treatment. 2021
Developing social life cycle assessment based on corporate social responsibility: A chemical process industry case regarding human rights
Tsalidis et al.
Technological Forecasting & Social Change. 2021
Social Life Cycle Assessment of Brine Treatment in the Process Industry: A Consequential Approach Case Study
Tsalidis et al.
Sustainability. 2019
Industrial Symbiosis: towards a design process for eco-industrial clusters by integrating Circular Economy and Industrial Ecology perspectives
Baldassarre et al.
Journal of Cleaner Production. 2019
Electrodialysis of coal mine water
Mitko et al.
Water Resources and Industry. 2021.
Redesigning the coal mine wastewater treatment to enable transition to circular economy practices
The ZERO BRINE and Dębieńsko case studies
SDEWES, 2021
Modelling of an innovative membrane crystallizer for the production of Magnesium Hydroxide from waste brine
C.Morgante, Universita degli Studi di Palermo
EUROMEMBRANE, 2021

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